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A standard state is a particular state of a species at temperature T and at specified conditions of pressure, composition, and physical condition as, eg, gas, liquid, or solid A standard-state pressure of 1 standard atmosphere (101325 kPa) was in use for many years, and older data tabulations are for this pressure The standard is now 1 bar (lo5 Pa), but for purposes of this chapter, the difference is of negligible consequence With respect to composition, the standard states used in this chapter are states of thepure species For gases, the physical state is the ideal-gas state and for liquids and solids, the real state at the standard-state pressure and at the system temperature In summary, the standard states used in this chapter are:

Every time you paste in a new layer, be sure to set the blend for that new layer to Multiply, or the added layers will have no effect on the color of the sky

Gases: The pure substance in the ideal-gas state at 1 bar Liquids and solids: The real pure liquid or solid at 1 bar

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The definition of the chemical potential by Eq (111) as the mole-number derivative of nG suggests that other derivatives of this kind should prove useful in solution thermodynamics Thus,

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This equation defines the partial molar property of species i in solution, where the generic symbol Mi may stand for the partial molar internal energy U ; ,the partial molar enthalpy Hi, the partial molar entropy Si, the partial molar Gibbs energy G i ,etc It is a response function, representing the change of total property n M due to addition at constant T and P of a differential amount of species i to a finite amount of solution Comparison of Eq (111) with Eq (117) written for the Gibbs energy shows that the chemical potential and the partial molar Gibbs energy are identical; ie,

The multiply technique is not the only way to punch up a lame sky You can also steal the sky from another photo, as I ll show you how to do now For starters, though, you re going to need a great photo of the sky When I see a pretty blue sky, a swirling, cloudy day, a stormy afternoon, or a beautiful sunset, I grab my camera and start shooting Use the Exposure Lock feature on your camera to set the exposure based on the sky or simply fill the entire frame with sky either way, you ll capture all the color and intensity that you see through the viewfinder in the final image Shoot your sky shots with your camera s highest resolution, since you never know what resolution you ll eventually need You might also want to take some pictures in landscape mode and others in portrait mode so you have a selection of skies for any situation Store your collection of sky images in a special folder, and you ll always have options available when you want to replace a bland sky

The standard addition operator. Remember, just because the operator is called the addition operator doesn t mean that you have to retain that connotation. However, you should attempt to overload the operators as close to their original meaning as possible. Visual Basic itself overloads this operator to let it act a little like the string concatenation operator. This is the unary negation operator that comes just before a value or expression. The subtraction operator, although if you can figure out how to subtract one bumblebee from another, you re a better programmer than I am. The multiplication operator. The standard division operator. The integer division operator. Remember, you are not required to retain any sense of integer in this operator if it doesn t meet your class s needs.

The definition of a partial molar property, Eq (1 17), provides the means for calculation of partial properties from solution-property data Implicit in this definition is another, equally important, equation that allows the reverse, ie, calculation of solution properties from knowledge of the partial properties The derivation of this equation starts with the observation that the thermodynamic properties of a homogeneous phase are functions of temperature, pressure, and the numbers of moles of the individual species which comprise the phase1 Thus for thermodynamic property M:

The total differential of n M is:

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